Guo Xianghai
School
School of Chemical Engineering and Technology
Professional Title
Professor
Administrative Appointments
Deputy head, Dept. of Pharma. Eng.
Discipline
Chemical Engineering
Contact Information
13920406411
Guoxh@tju.edu.cn
Department of Pharmaceutical Engineering, School of Chemical Engineering and Technology, Tianjin University
Education Background
- Ph. D.| Tianjin University| Applied Chemistry| 2006
- Master| Tianjin University| Industrial Catalysis| 2001
- Bachelor| Tianjin University| Industrial Catalysis| 1998
Research Interests
- Adsorption
- Catalysis
- Membrane separation
- Design, synthesis and applications of metal-organic frameworks
- Design, synthesis and applications of hierarchical zeolites
Professional Membership
- The Chemical Industry and Engineering Society of China
- Chinese Chemical Society
- American Chemical Society
Positions & Employments
-
2010.2-Now
School of Chemical Engineering and Technology | Tianjin University -
2006.5-2010.1
School of Pharmaceutical Science and Technology | Tianjin University -
2001.7-2002.5
Tianjin UnivTech Co. Ltd.
Academic Achievements
- Papers
- [1] Lyu, J.; Gong, X.; Lee, S.-J.; Gnanasekaran, K.; Zhang, X.; Wasson, M. C.; Wang, X.; Bai, P.; Guo, X.; Gianneschi, N. C.; Farha, O. K.*, Phase Transitions in Metal-Organic Frameworks Directly Monitored through In Situ Variable Temperature Liquid-Cell Transmission Electron Microscopy and In Situ X-ray Diffraction. J. Am. Chem. Soc. 2020, 142 (10), 4609-4615.
- [2] Chen, T.; Wang, Q.; Lyu, J.; Bai, P.; Guo, X.*, Boron removal and reclamation by magnetic magnetite (Fe3O4) nanoparticle: An adsorption and isotopic separation study. Sep. Purific. Tech. 2020, 231, 115930.
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- [3] Lyu, J.; Zhang, X.; Li, P.; Wang, X.; Buru, C. T.; Bai, P.; Guo, X.; Farha, O. K*. Exploring the Role of Hexanuclear Clusters as Lewis Acidic Sites in Isostructural Metal–Organic Frameworks. Chem. Mater. 2019, 31(11), 4166-4172.
- [4] Lyu, J.; Zhang, X.; Otake, K.; Wang, X.; Li, P.; Li, Z.; Chen, Z.; Zhang, Y.; Wasson, M. C.; Yang, Y.; Bai, P.; Guo, X.; Islamoglu, T.; Farha, O. K.*, Topology and porosity control of metal-organic frameworks through linker functionalization. Chem. Sci. 2019, 10 (4), 1186-1192.
- [5] Lyu, J.; Zhang, X.; Chen, Z.; Anderson, R.; Wang, X.; Wasson, M. C.; Bai, P.; Guo, X.; Islamoglu, T.; Gomez-Gualdron, D. A.; Farha, O. K.*, Modular Synthesis of Highly Porous Zr-MOFs Assembled from Simple Building Blocks for Oxygen Storage. ACS Appl. Mater. Interfaces 2019, 11 (45), 42179-42185.
- [6] He, Z.; Yang, Y.; Bai, P.; Guo, X.*, Metal-Organic Framework MIL-53(Cr) as a Superior Adsorbent: Highly Efficient Separation of Xylene Isomers in Liquid Phase. J. Ind. Eng. Chem. 2019, 77, 262–272.
- [7] Liu, H.; Yu, C.; Bai, P.; Guo, X.*, Novel Isopropoxy Group-Functionalized UiO-66 with a High Hydrogen Chloride Adsorption Capacity. J. Chem. Eng. Data 2019, 64(8), 3576-3584.
- [8] Yu, C.; Liu, H.; Lyu, J.; Xiao, Z.; Bai, P.; Guo, X*. Tuning Adsorption Capacity by Alkoxy Groups: A Study on Acetic Acid Adsorption on UiO-66 Analogues from Aqueous Solution. Ind. Eng. Chem. Res. 2019, 58 (27), 12272-12279.
- [9] Liu, H.; Lan, X.; Bai, P.; Guo, X.*, Alkoxy-Group-Functionalized UiO-66 as Highly Efficient Adsorbents for Hydrogen Chloride Removal from Aqueous Solution. J. Chem. Eng. Data 2019, 64 (1), 286-295.
- [10] Chen, Y.; Lyu, J.; Wang, Y.; Chen, T.; Tian, Y.; Bai, P.; Guo, X.*, Synthesis, Characterization, Adsorption, and Isotopic Separation Studies of Pyrocatechol-Modified MCM-41 for Efficient Boron Removal. Ind. Eng. Chem. Res. 2019, 58 (8), 3282-3292.
- [11] Xiao, Z.; Zhang, J.; Ding, H.; Cheng, Y.; Bai, P.; Guo, X.*, n-C22H45N+(CH3)2CH2(CH2)4CH2N(CH3)2Br−: A new effective one-step structure directing agent to synthesize hierarchical MFI zeolite with ordered hexagonal mesopores. Microporous Mesoporous Mater. 2019, 273, 142-147.
- [12] Zeng, Z.; Lyu, J.; Bai, P.; Guo, X.*, Adsorptive Separation of Fructose and Glucose by Metal-Organic Frameworks: Equilibrium, Kinetic, Thermodynamic, and Adsorption Mechanism Studies. Ind. Eng. Chem. Res. 2018, 57 (28), 9200-9209.
- [13] Ding, H.; Zhang, Y.; Xiao, Z.; Zhang, J.; Bai, P.; Li, N.; Guo, X.*, Synthesis of Hierarchically Porous Zeolite Composites with Enhanced Catalytic Activity: Effect of Different Long-Chain Structure Directing Agents. Cryst. Growth Des. 2018, 18 (3), 1730-1737.
- [14] Zhou, F.; Zhang, J.; Fu, T.; Bai, P.; Bai, P.; Guo, X.*, Theoretical study on complexes and reactions of boron isotopic exchange separation with fluorinated anisoles as novel donors. J. Radioanal. Nucl. Chem. 2018, 316 (2), 587-594.
- [15] Ding, H.; Xiao, Z.; Zhang, J.; Fu, T.; Bai, P.; Guo, X.*, Hierarchical Hexagonal Zeolites: Intrinsic Transformation Directed by Precise Control of Synthetic Conditions. Ind. Eng. Chem. Res. 2018, 57 (15), 5282-5290.
- [16] Ding, H.; Chen, Y.; Fu, T.; Bai, P.; Guo, X.*, Nanosheet-based magadiite: a controllable two-dimensional trap for selective capture of heavy metals. J. Mater. Chem. A 2018, 6 (28), 13471–13982.
- [17] Zhang, N.; Lyu, J.; Bai, P.; Guo, X.*, Boron isotopic separation with pyrocatechol-modified resin by chromatography technology: Experiment and numerical simulation. Journal of Industrial and Engineering Chemistry 2018, 57, 244-253.
- [18] Zhang, J.; Ding, H.; Zhang, Y.; Yu, C.; Bai, P.; Guo, X.*, An efficient one-pot strategy for synthesizing hierarchical aluminosilicate zeolites using single structure directing agent. Chem. Eng. J. 2018, 335, 822-830.
- [19] Lyu, J.; Zhang, N.; Liu, H.; Zeng, Z.; Zhang, J.; Bai, P.; Guo, X.*, Adsorptive removal of boron by zeolitic imidazolate framework: kinetics, isotherms, thermodynamics, mechanism and recycling. Separation and Purification Technology 2017, 187, 67-75.
- [20] Ding, H.; Ni, X.; Zhang, Y.; Zhang, J.; Zeng, Z.; Qi, M.; Bai, P.; Guo, X.*, Synthesis of b-oriented MFI nanosheets with high-aspect ratio by suppressing intergrowth with 2D GO nanosheets. CrystEngComm 2017, 19 (24), 3263-3270.
- [21] Ding, H.; Zhang, Y.; Ni, X.; Zhang, J.; Zeng, Z.; Bai, P.; Guo, X.*, Growth of two-dimensional silicalite-1 on graphene oxide with controllable electrical conductivity. RSC Adv. 2017, 7 (29), 17629-17632.
- [22] Lyu, J.; Liu, H.; Zhang, J.; Zeng, Z.; Bai, P.; Guo, X.*, Metal-organic frameworks (MOFs) as highly efficient agents for boron removal and boron isotope separation. RSC Adv. 2017, 7 (26), 16022-16026.
- [23] Lyu, J.; Liu, H.; Zeng, Z.; Zhang, J.; Xiao, Z.; Bai, P.; Guo, X.*, Metal-Organic Framework UiO-66 as an Efficient Adsorbent for Boron Removal from Aqueous Solution. Ind. Eng. Chem. Res. 2017, 56 (9), 2565-2572.
- [24] Zhou, F.; Zhang, J.; Bai, P.; Guo, X.*, Theoretical Calculation of Boron Isotopic Separation Factors in Ion-Exchange Chromatography. Journal of Chemical & Engineering Data 2017, 62 (1), 525-531.
- [25] Liu, M.-M.; Mei, Q.; Zhang, Y.-X.; Bai, P.; Guo, X.-H. *, Palladium-catalyzed amination of chloro-substituted 5-nitropyrimidines with amines. Chinese Chemical Letters 2017, 28 (3), 583-587.
- [26] Lyu, J.; Zeng, Z.; Zhang, N.; Liu, H.; Bai, P.; Guo, X.*, Pyrocatechol-modified resins for boron recovery from water: Synthesis, adsorption and isotopic separation studies. Reactive & Functional Polymers 2017, 112, 1-8.
- [27] Yang, Y.; Fan, K.; Bai, P.; Guo, X.*, Isobaric Vapor-Liquid Equilibrium Data for the Binary System of Water + 2-Methylpyridine at 101.3, 60.0, and 20.0 kPa. Journal of Chemical & Engineering Data 2017, 62 (2), 684-690.
- [28] Wang, Z.; Li, S.; Wang, C.; Guo, X.; Bai, P., Dynamic-accumulative operation policy of continuous distillation for the purification of anisole. Polish Journal of Chemical Technology 2016, 18 (1), 33-39.
- [29] Zhao, J.; Wang, B.; Bai, P.; Guo, X.; Ding, H., Intermittent feeding batch distillation with liquid exchange between two columns for separation of binary mixtures. Chemical Engineering and Processing 2016, 99, 41-50.
- [30] Bai, P.; Fan, K.; Guo, X. *; Zhang, H., Non-equilibrium mass transfer absorption model for the design of boron isotopes chemical exchange column. Annals of Nuclear Energy 2016, 92, 16-20.
- [31] Guo, X. *; Han, B., Dr. Jia-Xiang Shen: a pioneer of the Chinese pharmaceutical industry. Protein & cell 2016, 7 (8), 545-7.
- [32] Zhang, H. H.; Lan, X. Y.; Bai, P.; Guo, X. H. *, Adsorptive removal of acetic acid from water with metal-organic frameworks. Chemical Engineering Research & Design 2016, 111, 127-137.
- [33] Lan, X.; Zhang, H.; Bai, P.; Guo, X. *, Metal organic frameworks for adsorptive removal of hydrochloride from dilute aqueous solution. Microporous and Mesoporous Materials 2016, 231, 40-46.
- [34] Zhang, H.; Xiao, Q.; Guo, X.; Li, N.; Kumar, P.; Rangnekar, N.; Jeon, M. Y.; Al-Thabaiti, S.; Narasimharao, K.; Basahel, S. N.; Topuz, B.; Onorato, F. J.; Macosko, C. W.; Mkhoyan, K. A.; Tsapatsis, M., Open-Pore Two-Dimensional MFI Zeolite Nanosheets for the Fabrication of Hydrocarbon-Isomer-Selective Membranes on Porous Polymer Supports. Angewandte Chemie, International Edition, 2016, 55, 7184 –7187.
- [35] Zhimin Guan, Jiafei Lv, Peng Bai, Xianghai Guo*. Boron removal from aqueous solutions by adsorption — A review, Desalination, 2016, 383, 29–37.
- [36] Huanhuan Zhang, Yuming Wang, Peng Bai, Xianghai Guo*, Xiuxiu Ni. Adsorptive Separation of Acetic Acid from Dilute Aqueous Solutions: Adsorption Kinetic, Isotherms, and Thermodynamic Studies. J. Chem. Eng. Data, 2016, 61, 213−219.
- [37] Caijiao Wang, Peng Bai, Xianghai Guo. Advances in separation methods for large-scale production of silicon isotopes. J Radioanal Nucl Chem, 2015, 304, 989–999.
- [38] Li Bao, Peng Bai, Xianghai Guo*. Renewable Chemicals: Production or Purification by Adsorption Process. Journal of Dispersion Science and Technology, 2015, 36, 1297–1308.
- [39] 张欢欢，葛志强，郭翔海*，白鹏. 从工业废水中回收乙酸的方法研究进展. 化工进展, 2015, 34(6), 1768-1778.
- [40] Wang, Boyang，Lin, Hong，Guo, Xianghai，Bai, Peng*，Boron removal using chelating resins with pyrocatechol functional groups，Desalination，2014，347：138-143.
- [41] Wang, Boyang，Guo, Xianghai，Bai, Peng*，Removal technology of boron dissolved in aqueous solutions - A review，Colloids and Surfaces A: Physicochemical and Engineering Aspects，2014，444：338-344.
- [42] Wu, Xiaoqin，Bai, Peng*，Guo, Xianghai，He, Nana，2,4-Difluoro anisole: a promising complexing agent for boron isotopes separation by chemical exchange reaction and distillation，Journal of Radioanalytical and Nuclear Chemistry，2014，300（3）：897-902.
- [43] Guo, Xianghai*，Shen, Jiaxiang，An environmentally benign approach to the synthesis of thymine via hydroformylation of methyl acrylate，Monatshefte fur Chemie，2014，145（4）：657-661.
- [44] Shuo Zhao，Peng Bai，Xianghai Guo，Ke Tang，Guangzhong Li，Time requirements in closed and open batch distillation arrangements for separation of a binary mixture，Pol. J. Chem.Technol.，2014，16（4）：66-74.
- [45] 刘亚君，郭翔海，白鹏，近年碳环核苷类似物的合成研究进展，有机化学，2014，34（11）：2202-2216.
- Patents
- [1] Guo, X.; Zhang, J.; Yu, C. Synthesis method of multistage ordered mesoporous aluminosilicate zeolite. 2017-10764491, CN107572547, 20170830., 2018.
- [2] Guo, X.; Zhang, J.; Yu, C. Direct synthesis method of multi-stage ordered mesoporous molecular sieve. 2017-10763659, CN107651693, 20170830., 2018.
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- [3] Guo, X.; Lv, J.; Bai, P. Boron - 11 isotope in integrated circuit for semiconductor doped and its application in method [Machine Translation]. 2017-10793131, CN107680904, 20170904., 2018.
- [4] Guo, X.; Liu, H.; Bai, P. Use of ether-containing functional group metal-organic framework material for adsorbing acetic acid in waste acid solution. 2017-10728860, CN107552005, 20170823., 2018.
- [5] Guo, X.; Zhang, J.; Yu, C. A kind of direct synthesis method of multi-stage ordered mesoporous molecular sieve [Machine Translation]. 2017-10763659, CN107651693, 20170830., 2018.
- [6] Guo, X.; Zhang, J.; Yu, C. Synthetic method of meso-microporous composite molecular sieve catalyst. 2017-10763658, CN107497480, 20170830., 2017.
- [7] Guo, X.; Lv, J.; Bai, P. Removal method of boron from water by metal organic frameworks. 2017-10307909, CN106984274, 20170504., 2017.
- [8] Guo, X.; Lv, J.; Bai, P. Method for separating boron isotopes by using catechol chelating resin as stationary phase of simulated moving bed. 2017-10307548, CN107008150, 20170504., 2017.
- [9] Guo, X.; Lv, J.; Bai, P. Catechol chelate resin and preparation method thereof. 2017-10307910, CN107011466, 20170504., 2017.
- [10] Guo, X.; Lv, J.; Bai, P. Method for separating boron isotope by using metal organic framework material as simulated moving bed stationary phase. 2017-10307546, CN107020014, 20170504., 2017.
- [11] Guo, X.; Lv, J.; Bai, P. Application of metal-organic framework material in separation of boron isotope. 2017-10307529, CN107096383, 20170504., 2017.
- [12] Guo, X.; Lv, J.; Bai, P. Method for separating boron isotopes from metal-organic framework materials as simulated moving bed stationary phase. 2017-10719611, CN107376646, 20170821., 2017.
- [13] Guo, X.; Lv, J.; Bai, P. Method for separating boron isotopes with MOF-74(Zn) as stationary phase of simulated moving bed. 2017-10718908, CN107413195, 20170821., 2017.
- [14] Guo, X.; Liu, H.; Bai, P. Application of metal-organic framework material containing ether functional group in adsorption of hydrochloric acid in waste acid solution. 2017-10728811, CN107469775, 20170823., 2017.
- [15] Guo, X.; Ding, H.; Bai, P. Preparation method of new MFI molecular sieve/graphene oxide nanosheet composite with good electrical conductivity. 2017-10152458, CN106904630, 20170315., 2017.
- [16] Guo, X.; Lv, J.; Bai, P. Application of metal-organic framework material in removing boron from water. 2017-10307909, CN106984274, 20170504., 2017.
- [17] Guo, X.; Lv, J.; Bai, P. Catechol chelating resin and preparation method. 2017-10307910, CN107011466, 20170504., 2017.
- [18] Guo, X.; Wang, B.; Bai, P. Application of modified resin in boron removal process for industrial wastewater treatment. 2013-10614001, CN104671322, 20131126., 2015.
- [19] Guo, X.; Lv, L.; Bai, P. Process for preparing D-fructose and D-mannose by isomerization of D-glucose. 2013-10743577, CN104744523, 20131226., 2015.
- [20] Guo, X.; Lv, L.; Bai, P. Process for preparation of D-fructose and D-mannose with simulated moving bed reactor. 2013-10743606, CN104744524, 20131226., 2015.
- [21] Guo, X.; Bao, L.; Bai, P.; Zhao, H. Method for separation of boron isotopes with boron specific resin as simulated moving bed stationary phase. 2013-10531015, CN103623700, 20131030., 2014.
- [22] Guo, X.; Ding, J.; Zengzhou, L.; Liu, N. Preparation of 1α-hydroxy vitamin D3 used as drug for treating osteoporosis. 2012-10494524, CN103073468, 20121127., 2013.
- [23] Guo, X.; Shen, J. Method for synthesizing thymine. 2007-10060002, CN101143850, 20071023., 2008.
- [24] Guo, X.; Shen, J. Process for preparation of indole. 2006-10015498, CN1911912, 20060830., 2007.
- [25] Guo, X.; Shen, J. Method for preparation of 5-methoxyindole. 2006-10016357, CN1944405, 20061030., 2007.
Team
Pharmaceutical Separation Engineering